Product Details
|
Synthesis Reference(s) |
The Journal of Organic Chemistry, 46, p. 4617, 1981 DOI: 10.1021/jo00335a076 |
InChI:InChI=1/C11H7BrO/c12-11-9(7-13)6-5-8-3-1-2-4-10(8)11/h1-7H
Axially chiral compounds can be synthesi...
Methyl (α-naphthyl) acrylates bearing an...
A facile and efficient strategy for the ...
New flavin-based photocatalytic systems ...
The present invention relates to an orga...
1-bromo-2-(bromomethyl)naphthalene
1-bromo-2-naphthaldehyde
| Conditions | Yield |
|---|---|
|
With
2-nitropropane; sodium ethanolate;
In
ethanol;
at 21 - 24 ℃;
for 18h;
|
97% |
|
With
silver nitrate;
In
water; acetone;
|
80% |
|
With
2-nitropropane; sodium ethanolate;
In
ethanol;
|
78% |
|
With
4-methylmorpholine N-oxide;
In
acetonitrile;
at 0 - 20 ℃;
for 6h;
Molecular sieve;
Inert atmosphere;
|
73% |
|
With
2-nitropropane; sodium ethanolate;
In
ethanol;
for 6h;
Heating;
|
62% |
|
With
ethanol; hexamethylenetetramine;
|
|
|
With
hexamethylenetetramine; acetic acid;
|
|
|
With
hydrogenchloride; N4(CH2)6; acetic acid;
Yield given. Multistep reaction;
|
|
|
With
2-nitropropane; sodium ethanolate;
In
ethanol;
at 20 ℃;
for 65h;
|
|
|
Multi-step reaction with 2 steps
1: 95 percent / aq. CaCO3 / dioxane / 10 h / Heating
2: 79 percent / pyridinium chlorochromate (PCC)
With
pyridinium chlorochromate; calcium carbonate;
In
1,4-dioxane;
|
(1-bromo-2-naphthyl)methanol
1-bromo-2-naphthaldehyde
| Conditions | Yield |
|---|---|
|
With
pyridinium chlorochromate;
In
dichloromethane;
for 1h;
|
97% |
|
With
pyridinium chlorochromate;
In
dichloromethane;
at 20 ℃;
for 1.5h;
|
89% |
|
With
pyridinium chlorochromate;
|
79% |
1-bromo-2-(bromomethyl)naphthalene
1-bromo-2-(methoxymethyl)naphthalene
benzenesulfinic acid cyclohexylamide
(1-bromo-2-naphthyl)methanol
1-bromo-α-phenyl-2-naphthalenemethanol
3-(1-bromo-[2]naphthyl)-2-phenyl-acrylic acid
(Z)-2-benzyloxycarbonylamino-3-(1-bromonaphthalen-2-yl)-acrylic acid methyl ester
1-(1-naphthyl)-naphthalene-2-carbaldehyde
CAS:1638121-62-6
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